How does sodium aluminate improve the folding endurance of paper?
Oct 02, 2025
As a dedicated supplier of Sodium Aluminate for Paper Making, I've witnessed firsthand the remarkable impact this chemical compound has on paper quality, particularly in enhancing the folding endurance of paper. In this blog, I'll delve into the science behind how sodium aluminate achieves this improvement, and why it's a game - changer for the paper industry.
Understanding Folding Endurance in Paper
Folding endurance is a crucial property of paper, which refers to the number of times a paper specimen can be folded back - and forth at a specific point under a defined load before it breaks. This characteristic is of utmost importance in various paper applications, such as packaging materials, books, and map papers. High folding endurance ensures that the paper can withstand repeated bending and manipulation without tearing, thereby maintaining its integrity and functionality over time.
The Role of Sodium Aluminate in Paper Making
Sodium aluminate, with the chemical formula NaAlO₂, is a white, crystalline solid that is highly soluble in water. It is commonly used in the paper - making process as a precipitating agent, sizing agent, and pH regulator. When added to the paper pulp, sodium aluminate interacts with other components in the pulp, leading to a series of physical and chemical changes that ultimately enhance the folding endurance of the paper.
1. Fiber Bonding Enhancement
One of the primary ways sodium aluminate improves folding endurance is by enhancing the bonding between paper fibers. In the paper - making process, fibers are suspended in water to form a pulp. The addition of sodium aluminate causes the fibers to come closer together and form stronger hydrogen bonds. This is because sodium aluminate hydrolyzes in water to form aluminum hydroxide, which acts as a bridging agent between the cellulose fibers. The aluminum hydroxide particles adsorb onto the surface of the fibers, creating a sticky layer that promotes better fiber - to - fiber contact. As a result, the paper formed from this pulp has a more cohesive structure, which can withstand the stress of folding better.
For example, studies have shown that when a small amount of 1302 - 42 - 7 Sodium Aluminate is added to the pulp, the internal strength of the paper, which is closely related to folding endurance, can increase significantly. The improved fiber bonding reduces the likelihood of fiber separation during folding, preventing the formation of cracks and tears in the paper.
2. Sizing Improvement
Sizing is an important step in paper making that helps to control the paper's absorption of liquids, such as ink and water. Sodium aluminate can be used as a sizing agent in combination with other sizing materials, such as rosin. When added to the pulp, sodium aluminate reacts with the rosin to form an insoluble aluminum - rosin complex. This complex deposits on the surface of the paper fibers, creating a hydrophobic layer that reduces the paper's porosity.
A well - sized paper with reduced porosity has better folding endurance. This is because the hydrophobic layer protects the fibers from moisture penetration, which can weaken the fiber bonds. Moisture can cause the fibers to swell and become more flexible, making the paper more prone to tearing during folding. By improving the sizing efficiency, 37% Sodium Aluminate Content helps to maintain the integrity of the fiber structure, resulting in a paper that can withstand more folding cycles.
3. pH Regulation
The pH of the paper pulp plays a crucial role in the paper - making process. Sodium aluminate is an effective pH regulator, which can adjust the pulp's pH to an optimal range. In general, a slightly alkaline pH is preferred for paper making as it promotes better fiber dispersion and bonding.
When the pH of the pulp is too low (acidic), the cellulose fibers can be damaged, leading to a decrease in paper strength and folding endurance. On the other hand, a too - high pH can cause the fibers to become brittle. Sodium aluminate can be used to raise the pH of the pulp to a suitable level, typically around 7 - 9. By maintaining the proper pH, the chemical and physical properties of the fibers are preserved, and the paper's folding endurance is improved.


Case Studies and Real - World Applications
To illustrate the effectiveness of sodium aluminate in improving folding endurance, let's look at some real - world examples. A paper mill that produces packaging papers was facing issues with low folding endurance in their products. After conducting a series of tests, they decided to incorporate Liquid Sodium Aluminate into their paper - making process.
They added a specific dosage of liquid sodium aluminate to the pulp at the appropriate stage. The results were remarkable. The folding endurance of the packaging papers increased by up to 30%, which not only met but exceeded the industry standards. This improvement in folding endurance allowed the packaging papers to withstand the rigors of transportation and handling, reducing the number of damaged packages and improving customer satisfaction.
Another case involved a map paper manufacturer. Map papers require high folding endurance as they are often folded and unfolded multiple times. By using sodium aluminate in the paper - making process, the manufacturer was able to produce map papers with excellent folding properties. The papers could be folded and refolded numerous times without showing signs of wear and tear, making them ideal for long - term use.
Advantages of Using Our Sodium Aluminate for Paper Making
As a supplier of sodium aluminate for paper making, we offer several advantages to our customers. Our sodium aluminate products are of high purity and quality, ensuring consistent performance in improving folding endurance. We have a strict quality control system in place, from raw material sourcing to the final product packaging.
We also provide technical support to our customers. Our team of experts can help you determine the optimal dosage of sodium aluminate for your specific paper - making process, based on factors such as the type of fibers, pulp consistency, and desired paper properties. We understand that every paper mill is unique, and we are committed to providing customized solutions to meet your needs.
Conclusion
In conclusion, sodium aluminate is a powerful tool in the paper - making industry for improving the folding endurance of paper. Through its ability to enhance fiber bonding, improve sizing, and regulate pH, sodium aluminate can significantly enhance the physical properties of paper, making it more durable and resistant to folding.
If you are in the paper - making industry and are looking to improve the folding endurance of your products, we invite you to contact us for more information. Our team is ready to discuss your requirements and provide you with the best sodium aluminate solutions for your paper - making process. Let's work together to create high - quality paper products that meet the demands of the market.
References
- Hubbe, M. A., Rojas, O. J., & Venditti, R. A. (2008). Physical and chemical aspects of the fiber - fiber bond. Tappi Journal, 7(11), 91 - 101.
- Jayasekara, R., & van de Ven, T. G. M. (2002). Influence of pH and electrolyte on the surface properties of cellulosic fibers. Journal of Colloid and Interface Science, 254(1), 111 - 118.
- Biermann, C. J. (1996). Handbook of Pulp and Paper Technology. Academic Press.
