How is Sodium Metaaluminate Solid prepared?
Jul 11, 2025
Sodium metaaluminate solid, a compound with significant industrial applications, is widely used in water treatment, paper production, and the manufacturing of zeolites. As a leading supplier of sodium metaaluminate solid, I am often asked about the preparation process. In this blog post, I will delve into the detailed steps of how sodium metaaluminate solid is prepared.
Raw Materials
The primary raw materials for preparing sodium metaaluminate solid are aluminum hydroxide (Al(OH)₃) and sodium hydroxide (NaOH). Aluminum hydroxide is a white, crystalline powder that is commonly obtained from bauxite through the Bayer process. Sodium hydroxide, also known as caustic soda, is a highly caustic metallic base that is available in various forms, including solid flakes and pellets.
Reaction Principle
The preparation of sodium metaaluminate solid is based on the reaction between aluminum hydroxide and sodium hydroxide. The chemical equation for this reaction is as follows:
Al(OH)₃ + NaOH → NaAlO₂ + 2H₂O
This reaction is an acid - base reaction, where aluminum hydroxide acts as an acid and reacts with the strong base sodium hydroxide to form sodium metaaluminate and water.
Preparation Process
Step 1: Mixing the Raw Materials
The first step in the preparation process is to mix the aluminum hydroxide and sodium hydroxide in the appropriate ratio. The ratio of aluminum hydroxide to sodium hydroxide depends on the desired concentration of the sodium metaaluminate solution. Generally, a stoichiometric ratio is used to ensure complete reaction.
The raw materials are typically mixed in a reaction vessel, which is usually made of stainless steel or other corrosion - resistant materials. The mixing process is carried out under controlled conditions, such as temperature and agitation, to ensure uniform mixing.
Step 2: Heating the Mixture
After the raw materials are mixed, the mixture is heated to a specific temperature to initiate the reaction. The reaction between aluminum hydroxide and sodium hydroxide is an exothermic reaction, but external heating is often required to reach the optimal reaction temperature.
The temperature is usually maintained between 100 - 150°C, depending on the reaction conditions and the equipment used. Heating the mixture helps to speed up the reaction rate and ensure complete conversion of the raw materials.
Step 3: Reaction and Dissolution
As the mixture is heated, the reaction between aluminum hydroxide and sodium hydroxide takes place. The aluminum hydroxide gradually dissolves in the sodium hydroxide solution, forming sodium metaaluminate and water.
The reaction is monitored to ensure that it proceeds to completion. This can be done by analyzing the composition of the solution using various analytical techniques, such as titration or spectroscopy.
Step 4: Filtration
After the reaction is complete, the solution is filtered to remove any unreacted solids or impurities. Filtration is an important step to obtain a pure sodium metaaluminate solution.
A filter press or other filtration equipment is used to separate the solid particles from the liquid solution. The filtered solution is then collected for further processing.
Step 5: Concentration of the Solution
The next step is to concentrate the sodium metaaluminate solution. This is usually done by evaporating the water from the solution. Evaporation can be carried out using various methods, such as vacuum evaporation or atmospheric evaporation.
During the evaporation process, the water is removed from the solution, and the concentration of sodium metaaluminate increases. The evaporation is continued until the desired concentration of sodium metaaluminate is reached.
We offer different concentrations of sodium metaaluminate solid, such as 85% Concentration Of Sodium Metaaluminate and 80% Concentration Of Sodium Metaaluminate.
Step 6: Crystallization
Once the desired concentration is achieved, the concentrated solution is cooled to induce crystallization. Crystallization is the process by which the sodium metaaluminate solidifies from the solution.
The cooling rate and temperature are carefully controlled to obtain large, well - formed crystals. The crystals are then separated from the mother liquor by filtration or centrifugation.
Step 7: Drying
The final step in the preparation process is to dry the sodium metaaluminate crystals. Drying is carried out to remove any remaining moisture from the crystals.
The crystals are usually dried in a hot air dryer or a vacuum dryer at a temperature of around 100 - 120°C. The drying process is continued until the moisture content of the sodium metaaluminate solid is within the acceptable range.
Quality Control
Throughout the preparation process, strict quality control measures are implemented to ensure the quality of the sodium metaaluminate solid. Quality control parameters include the concentration of sodium metaaluminate, the purity of the product, and the particle size of the crystals.
Various analytical techniques, such as chemical analysis, X - ray diffraction, and particle size analysis, are used to monitor the quality of the product at different stages of the preparation process.
Applications of Sodium Metaaluminate Solid
Sodium metaaluminate solid has a wide range of applications in different industries.
In the water treatment industry, it is used as a coagulant aid to improve the efficiency of water treatment processes. It helps to remove impurities and suspended solids from water, making it suitable for drinking and industrial use.
In the paper industry, sodium metaaluminate solid is used as a sizing agent to improve the strength and water resistance of paper.
In the manufacturing of zeolites, it is used as a raw material to produce various types of zeolites, which are widely used in catalysts, adsorbents, and ion - exchange materials.


Conclusion
As a supplier of Solid Sodium Metaaluminate, I am committed to providing high - quality products that meet the needs of our customers. The preparation of sodium metaaluminate solid is a complex process that requires careful control of various parameters, such as raw material quality, reaction conditions, and quality control.
If you are interested in purchasing sodium metaaluminate solid for your industrial applications, please feel free to contact us for more information and to discuss your specific requirements. We are always ready to provide you with the best products and services.
References
- Kirk - Othmer Encyclopedia of Chemical Technology.
- Ullmann's Encyclopedia of Industrial Chemistry.
- Textbooks on inorganic chemical engineering.
