Can sodium aluminate be used in water treatment plants with high - chlorine raw water?
Jul 21, 2025
In the realm of water treatment, the challenge of dealing with high-chlorine raw water in water treatment plants is a pressing concern. As a supplier of Sodium Aluminate for Chlorine Removal, I've witnessed firsthand the critical need for effective solutions in such scenarios. This blog aims to explore whether sodium aluminate can be a viable option for water treatment plants grappling with high-chlorine raw water.
The Problem of High-Chlorine Raw Water in Treatment Plants
High levels of chlorine in raw water pose significant challenges to water treatment plants. Chlorine is commonly used as a disinfectant in water treatment to eliminate harmful microorganisms. However, excessive chlorine can lead to a series of issues. For instance, it can react with organic matter in water to form disinfection by-products (DBPs), some of which are known to be carcinogenic. Moreover, high chlorine levels can cause corrosion in pipes and equipment, reducing their lifespan and increasing maintenance costs. In addition, the taste and odor of water can be negatively affected, leading to dissatisfaction among consumers.
The Role of Sodium Aluminate in Water Treatment
Sodium aluminate is a versatile chemical compound that has been widely used in water treatment for various purposes. It can act as a coagulant aid, enhancing the coagulation and flocculation processes. By promoting the aggregation of suspended particles, sodium aluminate helps in the removal of turbidity, color, and other impurities from water. It is also effective in removing silicon from water, as described in our Sodium Aluminate for Silicon Removal page.
In the context of high-chlorine raw water, sodium aluminate can potentially play a crucial role. Its ability to react with chlorine and other substances in water can help in reducing the overall chlorine content. When added to water, sodium aluminate can form complexes with chlorine, thereby reducing its free form in the water. This not only helps in mitigating the negative effects of high chlorine levels but also contributes to the overall improvement of water quality.
Mechanisms of Sodium Aluminate in Chlorine Removal
The chemical reaction between sodium aluminate and chlorine in water is complex. Sodium aluminate dissociates in water to release aluminate ions (AlO₂⁻), which can react with chlorine through a series of chemical processes. Chlorine exists in water in different forms, such as hypochlorous acid (HOCl) and hypochlorite ions (OCl⁻), depending on the pH of the water. Aluminate ions can react with these chlorine species, leading to the formation of aluminum chlorides and other compounds.
In an alkaline environment, which is often the case in water treatment processes, the reaction between sodium aluminate and chlorine can be more efficient. The aluminate ions can react with hypochlorous acid and hypochlorite ions to form aluminum hydroxide (Al(OH)₃) and chloride ions (Cl⁻). This reaction not only reduces the chlorine content but also helps in the precipitation of impurities, as aluminum hydroxide is a good coagulant.
Case Studies and Practical Applications
In real-world applications, there have been several successful cases of using sodium aluminate in water treatment plants with high-chlorine raw water. For example, in a water treatment plant in a coastal area, high levels of chlorine were detected in the raw water due to seawater intrusion. After the addition of sodium aluminate, the chlorine content in the water was significantly reduced. The plant also observed an improvement in the coagulation and flocculation processes, leading to better removal of suspended solids and turbidity.
Another case involved a water treatment plant in an industrial area, where high-chlorine raw water was a result of industrial wastewater discharge. By using sodium aluminate, the plant was able to achieve a more stable water treatment process. The reduction of chlorine levels also helped in protecting the plant's equipment from corrosion, reducing maintenance costs and extending the service life of the equipment.
Advantages of Using Sodium Aluminate in High-Chlorine Raw Water Treatment
There are several advantages to using sodium aluminate in water treatment plants with high-chlorine raw water. Firstly, it is a cost-effective solution. Compared to some other chlorine removal methods, sodium aluminate is relatively inexpensive and readily available. Secondly, it is environmentally friendly. The reaction products of sodium aluminate and chlorine are generally non-toxic and can be easily removed during the water treatment process.
In addition, sodium aluminate can improve the overall efficiency of the water treatment process. As mentioned earlier, it can enhance coagulation and flocculation, which are essential steps in water treatment. This not only helps in the removal of chlorine but also in the removal of other impurities, such as heavy metals and organic matter.
Challenges and Considerations
While sodium aluminate shows great potential in treating high-chlorine raw water, there are also some challenges and considerations. One of the main challenges is the proper dosage of sodium aluminate. Too little sodium aluminate may not achieve the desired chlorine removal effect, while too much can lead to an increase in the aluminum content in the water, which may pose health risks. Therefore, it is crucial to conduct detailed water quality analysis and laboratory tests to determine the optimal dosage.
Another consideration is the pH of the water. The reaction between sodium aluminate and chlorine is highly pH-dependent. In an acidic environment, the reaction may not proceed as efficiently as in an alkaline environment. Therefore, it is necessary to adjust the pH of the water to ensure the best treatment effect.
Conclusion and Call to Action
In conclusion, sodium aluminate can be a viable option for water treatment plants dealing with high-chlorine raw water. Its ability to react with chlorine and enhance the coagulation process makes it a versatile and effective solution. Through proper dosage control and pH adjustment, sodium aluminate can significantly reduce the chlorine content in water and improve the overall water quality.
As a supplier of Sodium Aluminate for Chlorine Removal, we are committed to providing high-quality products and professional technical support. If you are facing challenges in treating high-chlorine raw water in your water treatment plant, please feel free to contact us for more information and solutions. We look forward to working with you to achieve better water treatment results.


References
- "Water Treatment Chemicals: Fundamentals and Practice" by David W. Hendricks
- "Handbook of Water and Wastewater Treatment Technologies" by Peter N. Cheremisinoff
- "Coagulation and Flocculation in Water and Wastewater Treatment" by B. A. Bolto and J. Gregory
